Sunday, October 15, 2023

Burning coal for nitrogen (and sulfuric acid)

Suppose I caught a mole of dry soot. The formula which Bergin's crew sent us was C100H75–79O11–17N3–4S1–3. Molar weight of its components: 1201+76+240+56+64 = 1.637 kg. If I burn that in oxygen (or in ozone, oxozone; whatever - pretend I have an infinitude to burn): I get 1201+3200 carbon-dioxide, 76+608 water, and 64+64 sulfur-dioxide (again, not caring about the oxygen). I'd get the same 56g nitrogen in, I hope, gas form.

I concede Concerns with carbon-monoxide, hydrogen-sulfide, hydrogen-cyanide but these should (mainly) be containable until the oxygen does its work. Too much oxygen and we get nitrous oxides, or water-peroxide - but most of all, I have a Feeling about sulfurous even sulfuric acid. In fairness, I can count on that 76:2 hydrogen:sulphur ratio. Two H2SO3 (or H2SO4) molecules will sequester all the sulfur and leave 72 hydrogens free to make 36 water molecules (72+576). A 1:18 acid:water solution is, I understand, diluted enough to work with. Some of the carbon-compounds will get dissolved into this too. At 295 K I hear 0.07 mol% CO2 just for water (pdf): so from the heated coal I estimate 0.2 molecules in solution leaving the other 100(-) loose as, mostly, free CO2 gas. Back to the fluid, don't splash it in your eyes.

So, should my stone space colony want 46.3 tonnes of nitrogen they'll need to burn 1637 × 46.3/56 tonnes of space-coal; a 1353 tonne sootball. Which is a sight better than a million tonnes. Hopefully they can find something like this within the rubble.

And the sulfuric acid looks like a nice little bonus. The pure water alone would make 648 × 46.3/56 = 535.75 tonnes which should offer a bit more in cubic meters. 50×5×2 m3 looks like a swimming pool.

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